Search results for "Defect free"
showing 4 items of 4 documents
PtTe2: Potential new material for the growth of defect-free TeO2 single crystals
2008
Abstract The dissociation of Te–O bonds is the main drawback, which hampers the yield of large-sized paratellurite single crystals of high optical quality when using platinum crucibles. In this work, it is assumed that a catalytic dissociation process involves the intermediate formation of platinum tellurides, these ones being then responsible for entrapment of gas bubbles and black precipitates when growth proceeds. To alleviate this difficulty, we suggest that platinum ditelluride could be a chemically more appropriate compound instead of pure platinum. First experiments on direct transformation of platinum sheets into PtTe 2 under tellurium gas atmosphere are described, as well as the pr…
Magnetoelectric coupling driven by inverse magnetostriction in multiferroic BiMn3Mn4O12
2013
By means of neutron powder diffraction, we investigated the effect of the polar Bi$^{3+}$ ion on the magnetic ordering of the Mn$^{3+}$ ions in BiMn$_3$Mn$_4$O$_{12}$, the counterpart with \textit{quadruple} perovskite structure of the \textit{simple} perovskite BiMnO$_3$. The data are consistent with a \textit{noncentrosymmetric} spacegroup $Im$ which contrasts the \textit{centrosymmetric} one $I2/m$ previously reported for the isovalent and isomorphic compound LaMn$_3$Mn$_4$O$_{12}$, which gives evidence of a Bi$^{3+}$-induced polarization of the lattice. At low temperature, the two Mn$^{3+}$ sublattices of the $A'$ and $B$ sites order antiferromagnetically (AFM) in an independent manner …
Optimal die Design for Cold Extrusion Processes
1999
The design of cold extrusion processes requires the optimisation of several process variables in order to obtain a defect free product. The fulfilment of different objectives, such as the minimisation of forming loads or the homogeneity of the deformations, is highly requested. Nevertheless, several other relevant aspects of extrusion processes have to be taken into account and require a suitable optimisation of the process parameters and in particular of the die shape. In this paper, tool life has been assumed as the most relevant goal and an effective die design procedure as been setup. It is well known that fatigue cracking of the dies is the principal cause of dies failure in cold extru…
Real-time Control of Metallurgic Processes
1996
The careful control of the liquid metal solidification and the solid shell growth is of central importance in all metallurgic processes. These have a considerable influence on the formation of cracks and other defects which can be formed in the cast material. To ensure defect free products, the liquid metal is to be cooled down according to a pattern which depends i.e. on metal grade, product dimension, cooling speed and machine design. On the other hand, the control of the liquid/solid interface is a key element in optimising the liquid solidification with respect to good productivity. So, the heat transfer plays a very important role in metallurgic casting processes, especially when casti…